RICINOLEIC ACID

PRODUCT IDENTIFICATION

CAS NO. 141-22-0; 8040-35-5; 17026-54-9; 25607-48-1; 45260-83-1

RICINOLEIC ACID 

EINECS NO. 205-470-2
FORMULA C18H34O3
MOL WT. 298.46

H.S. CODE

 

TOXICITY

 
SYNONYMS 12-hydroxy-(cis)-9-octadecenoic acid; ácido ricinoleico (Spanish); Acide ricinoleique (French);
L'acide Ricinoleique (French); Acide Ricinoleique; Castor Oil Acid; Cis-12-hydroxyoctadec-9-enoic Acid; D-12-hydroxyoleic Acid; Kyselina 12-hydroxy-9-oktadecenova; Kyselina Ricinolova; 12-hydroxy Oleic Acid; Ricinic Acid; Ricinolic Acid; Ricinolsäure (German);

SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Viscous yellow liquid

MELTING POINT

5.5 C

BOILING POINT 245 C
SPECIFIC GRAVITY 0.94

SOLUBILITY IN WATER

Insoluble
pH  
VAPOR DENSITY 10.3

AUTOIGNITION

 

NFPA RATINGS

 

REFRACTIVE INDEX

 

FLASH POINT

224 C

STABILITY Stable under ordinary conditions

GENERAL DESCRIPTION AND APPLICATIONS

Ricinoleic Acid, also called castor oil acid, belong to a family of the unsaturated fatty acid. It is a viscous yellow liquid, melting at 5.5 C and boiling at 245 C. It is insoluble in water but soluble in most organic solvents. It is prepared by the hydrolysis of Castor Oil. It is used in textile finishing, in coating, inks and in making soaps.
SALES SPECIFICATION

APPEARANCE

viscous yellow liquid
ACID VALUE 175 min
HYDROXYL VALUE 150 min
IODINE VALUE 80-91
SAPONIFICATION VALUE 180 min
COLOR, GARDNER

8 max

TRANSPORTATION
PACKING  
HAZARD CLASS  
UN NO.  
 

 Fatty Acids are aliphatic carboxylic acid with varying hydrocarbon lengths at one end of the chain joined to terminal carboxyl (-COOH) group at the other end. The general formula is R-(CH2)n-COOH. Fatty acids are predominantly unbranched and those with even numbers of carbon atoms between 12 and 22 carbons long react with glycerol to form lipids (fat-soluble components of living cells) in plants, animals, and microorganisms. Fatty acids all have common names respectively lilk lauric (C12), MyrIstic (C14), palmitic (C16), stearic (C18), oleic (C18, unsaturated), and linoleic (C18, polyunsaturated) acids. The saturated fatty acids have no solid bonds, while oleic acid is an unsaturated fatty acid has one solid bond (also described as olefinic) and polyunsaturated fatty acids like linolenic acid contain two or more solid bonds. Lauric acid (also called Dodecanoic acid) is the main acid in coconut oil (45 - 50 percent) and palm kernel oil (45 - 55 percent). Nutmeg butter is rich in myristic acid (also called Tetradecanoic acid ) which constitutes 60-75 percent of the fatty-acid content. Palmitic acid(also called Hexadecylic acid ) constitutes between 20 and 30 percent of most animal fats and is also an important constituent of most vegetable fats (35 - 45 percent of palm oil). Saturated carboxylic acids (C1 – C10) are liquids whereas long chain saturated fatty acids are solids. The long carbon chains form compact pile in a regular pattern with high van der waals attractions resulting in high melting points. If solid bonds are present in the fatty acid portion of the molecule, the fat is said to be unsaturated. Monounsaturated contains only one solid bond; polyunsaturated contains more than one solid bonds (up to an maximum of about six) which are never conjugated and can form geometric cis/trans isomers. Naturally occuring unsaturated fatty acids are liquids as they are in the cis- geometrical configuration which twists molecular structure (the kink of the cis form); can not pack closely, lowers melting points. Unsaturated fatty acids in the kinked, cis form are much more common in cells than the trans form continues in the same direction without a pronounced kink. The cis form of unsaturated fatty acids are more fluid at biological temperatures and are more abundant in living organisms. Fatty acids are named by the number of carbon atoms n and the number of solid bonds m as (n:m). The system for naming solid bond position is to indicate the first solid bond in the carbon backbone counting from the opposite end from the carboxyl group. The terminal carbon atom is called the omega carbon atom. The term "omega-3 or omega-6" signifies that their single solid bond is occured at carbon number 3 or 6 respectively counted from and including the omega carbon. Human bodies are not capable of synthesizing omega-3 and omega-6 fatty acids which are called essential fatty acids must be obtained through the diet. (These fatty acids were designated as "Vitamin F", until it was realized that they must be classified with the fats.) Fatty acids are converted to enegy through the process called fatty acid oxidation in liver cells. Fatty acids are used as basic building blocks of biological membranes, for long-term energy storage (the major components of triglycerides) as well as for the precursors of eicosanoid hormones.

COMMON NAME

SYSTEMATIC NAME

CAS RN

SYMBOL

Myristolenic Acid

(Z)-9-Tetradecenoic Acid

544-64-9

14:1 n-5

Palmitoleic Acid (Z)-9-Hexadecenoic Acid 373-49-9

16:1 n-7

Palmitelaidic Acid (E)-9-Hexadecenoic Acid 10030-73-6

16;1 n-7 (trans)

Vaccenic Acid (Z)-11-Octadecenoic Acid 506-17-2 18:1 n-7

Oleic Acid

(Z)-9-Octadecenoic Acid

112-80-1 18:1 n-9
Elaidic Acid (E)-9-Octadecenoic Acid 112-79-8 18:1 n-9 (trans)
Linoelaidicic Acid (E,E)-9,12-Octadecadienoic Acid 506-21-8

18:2 n-6 (trans)

Linoleic Acid (Z,Z)-9,12-Octadecadienoic Acid 60-33-3

18:2 n-6

Isolinoleic Acid (E,E)-9,11-Octadecadienoic Acid 544-71-8

18:2 n-6 (trans)

Linolenic Acid (Z,Z,Z)-9,12,15-Octadecatrienoic Acid 463-40-1 18:3 n-3
gamma -Linolenic Acid (Z,Z,Z)-6,9,12-Octadecatrienoic Acid 506-26-3 18:3 n-6

Moroctic Acid

(Z,Z,Z,Z)-6,9,12,15-Octadecatetraenoic Acid

20290-75-9

18:4 n-3
Eicosenoic Acid

(Z)-11-Ecosenoic Acid

5561-99-9 20:1 n-9
Eicosadienoic Acid

(Z,Z,)-11,14-Ecosadienoic Acid

2091-39-6 20:2 n-6
Mead Acid

(Z,Z,Z)-5,8,11-Eicosatrienoic Acid

20590-32-3 20:3 n-9

Eicosatrienoic Acid

(Z,Z,Z)-11,14,17-Eicosatrienoic Acid

17046-59-2

20:3 n-3
Dihomo-g -Linolenic Acid

(Z,Z,Z)-8,11,14-Eicosatrienoic Acid

1783-84-2 20:3 n-6
Omega-3 Arachidonic Acid

(Z,Z,Z,Z)-8,11,14,17-Eicosatetraenoic Acid

24880-40-8 20:4 n-3
Arachidonic Acid

(Z,Z,Z,Z)-5,8,11,14-Eicosatetraenoic Acid

506-32-1 20:4 n-6
Timnodonic Acid (Z,Z,Z,Z,Z)-5,8,11,14,17-Eicosapentaenoic Acid 10417-94-4 20:5 n-3
Erucic Acid

(Z)-13-Docosenoic Acid

112-86-7

22:1 n-9

Docosadienoic Acid

(Z,Z)-13,16-Docosadienoic Acid

17735-98-7

22:2 n-6

Docosatrienoic Acid

(Z,Z,Z)-13,16,19-Docosatrienoic Acid

28845-86-5

22:3 n-3

Adrenic Acid

(Z,Z,Z,Z)-7,10-13-16-Ocosatetraenoic Acid

28874-58-0

22:4 n-6

Docosapentaenoic Acid

(Z,Z,Z,Z,Z)-4,7,10,13,16-Docosapentaenoic Acid

25182-74-5

22:5 n-6

Docosapentaenoic Acid

(Z,Z,Z,Z,Z)-7,10,13,16,19-Docosapentaenoic Acid

24880-45-3

22:5 n-3

Docosahexaenoic Acid

(Z,Z,Z,Z,Z,Z)-4,7,10,13,16,19-Docosahexaenoic Acid

6217-54-5

22:6 n-3

Nervonic Acid

(Z)-15-Tetracosaenoic Acid

506-37-6 24:1 n-9
Tetracosahexaenoic Acid

((Z,Z,Z,Z,Z,Z)-6,9,12,15,18,21-Tetracosahexaenoic Acid

  24:6 n-3